If you have got yourself in a situation where qnap system volume is residing on a single SSD / HDD and you want to move to another single larger disk then there is no official way to do this - but its actually very easy.
step one - insert the new disk into a spare location on the NAS.
if your system volume is sde and the new disk is sdf then run the following command
If you are using entware on your NAS box - ( you really should be ) then you can
if you are cloning a 700G drive you can specify the size in pv
Will give you a nice status display:
When this is done. shutdown the NAS
Remove the 2 drives that you've been working with.
startup the NAS again - the NAS will complain about the storage volume missing - re-insert the new bigger disk - the NAS will find it and will stop complaining about the volume and pool